自由基反应在合成功能性C60衍生物及C60官能化修饰中的应用

Several novel radical reactions of [60]fullerene had been found and studied in this project, including the thermoinduced radical reactions with enamines or allylic amines and the the Mn(III) induced radical reactions with diallylic amines. Over 30 new [60]fullerene derivatives had been synthesized and well characterized by means of spectroscopies. The reactions of [60]fullerene with azomenthine ylides and with silyl enol ethers had also been studied.

功能性衍生物的合成和C60官能化修饰是化学的两个重要研究方向。本课题拟研究自由基型从υ谡饬椒矫娴挠τ茫ǎ?。光引发生物碱与C60反应合成有潜在生物活性的C60生物碱衍生物2。烯胺在热和光引发下与C60的新类型反应的研究和应用3。通过有机汞或锡试剂訡60进行官能化修饰。这些研究经过初步的尝试，部分已获得了理想的结果。