烯烃的笼内亲电加成----溶液中极性加成的创新研究体系

By imploying our radical methodology----co-generation, co-construction and time-probing,non-solvated hydrogen chlorides have been generated in the original solvent cage in electron-transferreactions. Based on careful product analysis, kinetic studies as well as EPR determination, we have established the mechanism of the addition of the non-solvated electrophile to the C=C double bond of side-chain of the electron-rich aromatic substrates,found the difference from the mechanism for the corresponding reactions carried out in bulk solution and exhibited the good examples of application of our cage-addition reactions in organic synthesis.

建立能在溶剂笼壁内生成未溶剂化的系列亲电试剂的电子转移反应体系，用动力学、EPR、CIDNP及产物分析研究这类裸体亲电试剂对芳醚电子供体侧链烯键的加成机理，并与溶液本体的反应结果和国外气相极性加成的离子回旋共振（ICR）研究进行比较，以确定我们创新的傲谇椎缂映伞狈椒ǖ氖视梅段Р⒖仄浜铣捎τ谩