绿色溶剂中氨基酸及多肽催化不对称直接aldol类反应研究
基本信息
结项摘要
以脯氨酸、精氨酸、组氨酸等天然手性氨基酸或由它们合成的多肽为有机小分子催化剂，研究它们在绿色溶剂中催化直接aldol、Mannich、Michael及其类似反应。通过研究这些催化反应的产物分布、区域选择性、立体选择性，并对其中的典型反应的机理进行实验和量子化学计算研究，揭示这类催化反应的基本规律。对该课题的研究其意义在于：一方面，由于氨基酸及多肽等手性有机小分子为催化剂的原料易得,在合成反应中又不
项目摘要
项目成果
{{i.achievement_title}}
{{i.achievement_title}}
暂无此项成果
数据更新时间：2023-05-31
其他相关文献
Altered Urinary Amino Acids in Children With Autism Spectrum Disorders
Altered Urinary Amino Acids in Children With Autism Spectrum Disorders
A steroid-salen conjugate for zinc ion recognition and its applications in test-strips, living cells imaging, and cascade recognition for dihydrogen phosphate
A steroid-salen conjugate for zinc ion recognition and its applications in test-strips, living cells imaging, and cascade recognition for dihydrogen phosphate
Recent advances in single metal atom-doped MoS2 as catalysts for hydrogen evolution reaction
Recent advances in single metal atom-doped MoS2 as catalysts for hydrogen evolution reaction
Rational design of porous starch/hyaluronic acid composites for hemostasis
Rational design of porous starch/hyaluronic acid composites for hemostasis
Synthesis of an oligomeric thickener for supercritical carbon dioxide and its properties
Synthesis of an oligomeric thickener for supercritical carbon dioxide and its properties
彭以元的其他基金
相似国自然基金
水相及胶束中氨基酸及多肽直接催化aldol类型反应
不对称催化的直接型插烯aldol反应及其在有机合成中的应用
手性吡哆醛仿生催化氨基酸衍生物的不对称aldol反应和Mannich反应的研究
不对称催化aldol反应过程中金属间协同效应与机理的研究